The δ60/58Ni Values of Twenty‐Six Selected Geological Reference Materials     

Weihan Li  Jian‐Ming Zhu  Decan Tan  Guilin Han  Zhouqiao Zhao  Guangliang Wu 《Geostandards and Geoanalytical Research》2020,44(3):523-535

The high‐precision δ^60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ^60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ^60/58Ni _{NIST SRM 986} values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ^60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories.  相似文献   

长江感潮河段潮波传播变化特征及影响因素分析     

黄竞争  张先毅  吴峥  刘锋  蔡华阳  杨清书 《海洋学报》2020,42(3):25-35

径潮相互作用是感潮河段水动力变化的典型特征，受其影响潮波传播具有明显的洪枯季及沿程变化。本文基于长江感潮河段天生港、江阴、镇江、南京、马鞍山及芜湖6个潮位站2002?2014年连续高低潮位资料及大通站月均流量数据，统计分析长江感潮河段潮波振幅衰减率、潮波传播速度及余水位坡度等传播特征值的洪枯季及沿程变化特征，并探讨这些潮波传播特征的变化规律及其主要影响因素。结果表明，潮波传播特征的洪枯季差异自上游至下游逐渐减小，其分界点位于天生港与江阴之间（其中，天生港和江阴站的多年平均洪枯季潮差差值约为0.01 m和?0.04 m）；径流动力对潮波衰减的影响主要位于江阴以上河段，江阴以下河段主要受潮汐动力控制；径流驱动下余水位坡度引起的余水位及水深增加，导致潮波传播的有效摩擦减小，当流量超过某个阈值时潮波振幅衰减反而减弱，特别是上游马鞍山-芜湖段最为明显，统计结果表明该河段流量阈值约为33 000 m3/s。本文分析结果作为前人研究的重要补充，可为长江河口感潮河段径潮相互作用机制研究及河口治理等提供基础参考。  相似文献   

秦皇岛近岸海域潮间带砂质沉积物中微塑料和重金属污染特征   总被引：1，自引：0，他引：1  

陈月琴  罗维  孙聪慧  吴光红 《海洋学报》2020,42(4):113-121

基于密度分离原理，利用饱和NaCl溶液对秦皇岛近岸海域潮间带砂质沉积物中的微塑料进行了浮选和分离提取，采用显微红外光谱方法分析附着在滤膜上的微塑料颗粒形貌和材质。结合扫描电子显微镜?能谱仪(Scanning Electron Microscopy Energy Dispersive Spectrometer，SEM-EDS)对微塑料样品进行微观形貌观察及微区成分的分析。并采用地累积指数(Geo Accumulation Indexes，I_geo)和富集系数(Enrichment Factors，EF)分析砂质沉积物中重金属Hg、Cd和Pb污染水平和富集特点。分析砂质沉积物中烧失量(Loss on Ignition，LOI)、总有机碳(Total Organic Carbon，TOC)、总氮(Total Nitrogen，TN)以及碳氮的稳定同位素组成(δ13C和δ15N)，探讨有机质的可能来源。结果表明:秦皇岛近岸海域潮间带砂质沉积物中有纤维类、发泡类、薄膜类3种微塑料，以纤维类的微塑料为主。微塑料表层富集有Si、Al、Mg、Fe和Ca等元素。沉积物中Hg和Cd富集水平较高，Pb富集水平较低。沉积物TOC和TN含量较低，LOI为TOC的1.6倍，δ13C、δ15N和TOC/TN的数值范围均显示有机质以海洋浮游植物藻类等海源为主。  相似文献   

2014年秋季渤海网采浮游植物群落结构   总被引：1，自引：0，他引：1  

张雪  王俊  马武  王宏  高燕  刘克奉 《海洋学报》2020,42(8):89-100

基于2014年秋季在渤海进行的水文、化学和生物方面的综合大面调查，研究了渤海网采浮游植物群落的结构特征，并结合文献资料，分析影响浮游植物群落结构形成的原因。结果显示:2014年渤海秋季共鉴定浮游植物3个门42属96种，其中以硅藻为主，为34属79种，占总物种的82%；甲藻门7属16种，占总物种的17%；金藻门1属1种。其中，角毛藻属的种类最多，共17种；其次为圆筛藻属，共13种。浮游植物总细胞丰度介于(0.71～72.15)×104 cells/m3，平均为13.88×104 cells/m3，硅藻与甲藻细胞丰度比值为2∶1，硅藻在莱州湾的细胞丰度极显著高于其他海区，甲藻在渤海中部海区的细胞丰度显著高于其他海区。浮游植物优势种主要为星脐圆筛藻(Coscinodiscus asteromphalus)、威氏圆筛藻(C. wailesii)、具槽帕拉藻(Paralia sulcata)、梭状角藻(Ceratium fusus)和夜光藻(Noctiluca scintillans)。渤海秋季浮游植物群落多样性水平分布不均，局部海域由于单一优势种过量繁殖多样性降低，低值区分布于辽东湾和渤海海峡海域。与历史同期资料对比，渤海海域浮游植物群落出现明显的物种演替现象，甲藻中的角藻逐渐兴起，其在渤海中部及辽东湾的优势地位已经超过角毛藻属和圆筛藻属，渤海秋季局部海区浮游植物群落结构已经由硅藻控制转为硅藻和甲藻共同控制。  相似文献   

渤海海域浮游病毒和浮游细菌的丰度变化与环境因子之间的耦联关系     

王彩霞  吴霖  王毅波  Paterson James S.  Mitchell James G.  胡晓珂 《海洋学报(英文版)》2020,39(6):72-83

Uncovering the role of environmental factors and finding critical factors which harbor significant fractions in governing microbial communities remain key questions in coastal marine systems. To detect the interactions between environmental factors and distributions of virio-and bacterioplankton in trophic coastal areas, we used flow cytometry to investigate the abundance of virio-and bacterioplankton covering 31 stations in the Bohai Sea of China. Our results suggested that the average abundance of total virus(TV) in winter(～2.29×10~8 particles/mL)was slightly lower than in summer(～3.83×10~8 particles/mL). The mean total bacterial abundance(TB) was much lower in winter(～2.54×107 particles/mL) than in summer(～5.43×10~7 particles/mL). Correlation analysis via redundancy analysis(RDA) and network analysis among virioplankton, bacterioplankton and environmental factors revealed that the abundances of viral and bacterial subpopulations depend on environmental factors. In winter, only temperature significantly influenced the abundances of virio-and bacterioplankton. In summer, in addition to temperature, both salinity and nutrient(SiO_2) had a remarkable impact on the distribution of virioand bacterioplankton. Our results showed a clear seasonal and trophic pattern throughout the whole water system, which revealed that temperature and eutrophication may play crucial roles in microbial distribution pattern.  相似文献   

冷泉系统甲烷气体渗漏的声学特征及潜在环境效应     

尉建功  吴婷婷  邓希光  于宗泽  王力峰 《海洋学报(英文版)》2020,42(5):133-144

The amount of methane leaked from deep sea cold seeps is enormous and potentially affects the global warming,ocean acidification and global carbon cycle. It is of great significance to study the methane bubble movement and dissolution process in the water column and its output to the atmosphere. Methane bubbles produce strong acoustic impedance in water bodies, and bubble strings released from deep sea cold seeps are called "gas flares"which expressed as flame-like strong backscatter in the water column. We characterized the morphology and movement of methane bubbles released into the water using multibeam water column data at two cold seeps. The result shows that methane at site I reached 920 m water depth without passing through the top of the gas hydrate stability zone(GHSZ, 850 m), while methane bubbles at site II passed through the top of the GHSZ(597 m) and entered the non-GHSZ(above 550 m). By applying two methods on the multibeam data, the bubble rising velocity in the water column at sites I and II were estimated to be 9.6 cm/s and 24 cm/s, respectively. Bubble velocity is positively associated with water depth which is inferred to be resulted from decrease of bubble size during methane ascending in the water. Combined with numerical simulation, we concluded that formation of gas hydrate shells plays an important role in helping methane bubbles entering the upper water bodies, while other factors, including water depth, bubble velocity, initial kinetic energy and bubble size, also influence the bubble residence time in the water and the possibility of methane entering the atmosphere. We estimate that methane gas flux at these two sites is 0.4×10~6–87.6×10~6 mol/a which is extremely small compared to the total amount of methane in the ocean body, however, methane leakage might exert significant impact on the ocean acidification considering the widespread distributed cold seeps. In addition, although methane entering the atmosphere is not observed, further research is still needed to understand its potential impact on increasing methane concentration in the surface seawater and gas-water interface methane exchange rate, which consequently increase the greenhouse effect.  相似文献   

Multiple Unmanned Underwater Vehicles Consensus Control with Unmeasurable Velocity Information and Environmental Disturbances Under Switching Directed Topologies     

Yan  Zhe-ping  Wu  Yi  Liu  Yi-bo  Ren  Hong-liang  Du  Xue 《中国海洋工程》2020,34(5):631-640

China Ocean Engineering - A consensus algorithm proposed in the paper is applied to tackle remarkable problems of unmeasurable velocities, the environmental disturbances, and the limited...  相似文献   

2014年春季渤海浮游植物群落结构   总被引：2，自引：1，他引：1  

张雪  王俊  高燕  王宏  马武  刘克奉  陈卫 《海洋科学》2020,44(6):45-55

基于2014年春季在渤海进行的水文、化学和生物方面的综合大面调查，研究了渤海浮游植物群落的结构特征，并结合文献资料，分析影响浮游植物群落结构形成的原因。结果显示：2014年渤海春季共鉴定浮游植物3门29属50种，以硅藻为主，还有少数甲藻和金藻。其中，硅藻门中圆筛藻属的种类最多，共12种，其次为角毛藻属，共5种。浮游植物总细胞丰度介于1.08×10⁴~181.09×10⁴个/m³，平均为25.47×10⁴个/m³。硅藻与甲藻细胞丰度比值为12：1，硅藻在物种数量和细胞丰度上均占有绝对优势，为渤海浮游植物的主要类群。浮游植物优势种主要为密联角毛藻（Chaetoceros densus）、斯氏几内亚藻（Guinardia striata）、具槽帕拉藻（Paralia sulcata）和夜光藻（Noctiluca scintillans）。渤海春季浮游植物群落多样性水平较低，且分布不均。渤海中部和渤海海峡海域由于单一优势种过量繁殖导致群落稳定性较差。与历史同期资料对比，渤海海域浮游植物群落出现明显的物种演替现象，角毛藻的优势地位显著性下降，斯氏几内亚藻首次在渤海大面调查中被记录为优势种。本研究为今后渤海环境生态系统和渔业资源变动的研究提供重要基础资料和参考依据。  相似文献   

Application of flocculation combined with vacuum preloading to reduce river-dredged sludge     

Feiyu Liu  Wenqing Wu  Jun Wang  Jun Hai  Yuanqiang Cai 《Marine Georesources & Geotechnology》2020,38(2):164-173

Abstract

To achieve the rapid dewatering of dredged sludge, the flocculation–vacuum-preloading method was tested indoors. In this study, the optimal mixing ratio of six flocculants was determined through the settling column test, and then the proposed method was tested. The water drainage and settlement were monitored during the test, while the soil moisture content and shear strength were measured after the test. The results show that all the flocculants had an optimal mixing ratio, and the addition of 0.8% FeCl₃ or 0.08% anionic polyacrylamide (APAM) in the sludge can better accelerate solid–liquid separation of the sludge. After the test, the water content in the sludge decreased from 140% to 60%. Compared with general vacuum preloading, the use of the proposed method increased the water drainage by 46.5% and 56.8% and decreased the soil volumes by 60.5% and 82.4% for FeCl₃ and APAM, respectively. Moreover, the corresponding shear strength was increased from 10 to 14 and 17?kPa. In addition, the use of APAM increased the solidification rate of heavy metals in the sludge to more than 80%, effectively inhibiting the migration of heavy metals.  相似文献   

Flexural performances of prestressed high strength concrete piles reinforced with hybrid GFRP and steel bars     

Ping Wu  Yang Guo  Dayong Zhu  Weiliang Jin  Zhenhua Zhang  Rongzhu Liang 《Marine Georesources & Geotechnology》2020,38(5):518-526

Abstract

This study developed prestressed high-strength concrete (PHC) piles reinforced with high-strength materials (glass fiber-reinforced polymer (GFRP) bars) for flexural performance enhancement. Flexural strengths and behaviors of PHC piles reinforced with hybrid GFRP and steel bars were experimentally investigated, respectively. Large-scale specimens with total lengths of 12,000?mm and diameters of 600?mm were constructed and tested under bending, accompanied by evaluation of effects of non-prestressed reinforcement type and longitudinal reinforcement ratio. J-factors were calculated to evaluate deformability of all the specimens. PHC piles reinforced with GFRP bars were demonstrated to have much higher flexural capacity than those reinforced with steel bars. Moreover, strains at the midspans of cross sections of all the specimens basically conformed to the assumption of plane section. Failure of PHC piles reinforced with GFRP bars was attributable to gradual concrete crushing, while that of PHC piles reinforced with steel bars resulted from steel yielding. Results of this study were expected to provide theoretical basis for wide engineering applications of PHC piles reinforced with hybrid GFRP bars and steel bars in marine structures.  相似文献